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PI AF 2.5 supports SQL AlwaysOn Availability Groups and it's the recommended/Best-practice HA SQL deployment . The "Installing PI AF 2012 with SQL Server AlwaysOn Availability Group" document outlines how to setup and configure AF And SQL Always on.
If you're having trouble configuring AF with SQL AlwaysOn, please don't hesitate to contact techsupport and they'll happily assist.
Thanks a lot for the reference Sam, exactly what I was looking for.