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PI ProcessBook is a graphics package that allows users to create dynamic, interactive graphics and trends featuring real-time PI System data. Data can be viewed from multiple sources, such as relational databases that expose ODBC-compliant interfaces, or AF 2.x data. Additionally, PI ProcessBook provides tools for analyzing data on the display and incorporates Microsoft Visual Basic for Applications (VBA), so that special activities or routine chores can be automated.
Supervisory Control and Data Acquisition (SCADA) is a control system architecture that uses computers, networked data communications and graphical user interfaces for high-level process supervisory management.(SCADA - Wikipedia)
While PI ProcessBook can be the user interface component, it does not replace all the functionality of a full fledged SCADA system.
Addl resources on PI ProcessBook
To state the obvious.
PI ProcessBook is an OSIsoft product while SCADA System is not.